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排序方式: 共有1495条查询结果,搜索用时 171 毫秒
1.
Jing Liu Xiu‐Mei Li Dong‐dong Shi Zhi‐guo Wen Pei‐Long Yang 《Biomedical chromatography : BMC》2019,33(12)
In recent years, the fingerprint of high‐performance liquid chromatography has been extensively applied in the identification and quality control of traditional Chinese medicine. It can be a potential protocol for assessing the authenticity, stability and consistency of traditional Chinese medicine and guaranteeing the expected biological activity. In this paper, a method using high‐performance liquid chromatography to identify and control the quality of the extract of Taraxacum mongolicum Hand.‐Mazz. (TME) was established. With this method, the correlation coefficients of the similarity of 10 batches were ≥0.994. The TME displayed a steady proliferative effect in Lactobacillus plantarum. In brief, this study successfully built a reliable, simple and efficient method to control and confirm the quality and the stability of biological activity of the TME. 相似文献
2.
ABSTRACTA novel BODIPY-based dye with highly emissive character was configured by Sonogashira coupling and routinely characterized by NMR and MS technology. The emission of dye was investigated in solution/film/solid and shows intensive emission. In solution, the emission peak appeared around 510 nm with little influence by the polar environment. The terthiophene plays an effective antenna effect, harvesting the light and transferring the energy to BODIPY. The pseudo Stoke's shift enlarged to ~170 nm in solution. In film, the emission peak shifted to 563 nm in polycarbonate matrix. And it shifted further to 585 nm in solid due to the highly twisted structure, which avoided closely regular-tight packing. The dye rendered an intense fluorescence, good optothermal stability, and high fluorescence quantum yield (0.55). The solid emission showed highly red emission with Commission Internationale de L'Eclairage (CIE) coordinates of (X = 0.69, Y = 0.31). Thus, the synthesized dye is idea candidate for emitting materials. 相似文献
3.
《印度化学会志》2023,100(1):100860
This study investigates the influence of synthesis processes such as sonication, sol-gel, and microwave on the production of highly crystalline Lanthanum oxide nanoparticles (La2O3) employing Lanthanum nitrate and Ammonium hydroxide (NH4OH) as precursors. X-ray diffraction (XRD), particle size analysis (DLS), Field emission scanning electron microscopy (FESEM), Fourier-transform infrared spectroscopy (FTIR), ultraviolet–visible absorption spectroscopy (UV–Vis), and electrochemical impedance spectroscopy (EIS) were used to examine the most effective processing method and its effects on the nanoparticle characteristics, such as structure, morphology, and optical and electrical behavior. Sonication produces La2O3 NPs with a smaller crystalline size, an agglomerated nanorod structure, a higher bandgap, and better electrical responsiveness than sol-gel and microwave techniques. Structural and optical characterization tests discovered this. The photocatalytic degradation activity of cationic Safranin and anionic Congo red dye exhibits degradation efficiency of around 90.13% and 89.66%, respectively. 相似文献
4.
In fields such as food and nutrition science or plant physiology, interest in untargeted profiling of flavonoids continues to expand. The group of flavonoids encompasses several thousands of chemically distinguishable compounds, among which are a number of isobaric compounds with the same elemental composition. Thus, the mass spectrometric identification of these compounds is challenging, especially when reference standards are not available to support their identification. Many different types of isomers of flavonoid glycoconjugates are known, i.e. compounds that differ in their glycosylation position, glycan sequence or type of interglycosidic linkage. This work focuses on the mass spectrometric identification of flavonoid glycoconjugate isomers possessing the same glycan mass and differing only in their aglycone core. A non‐targeted HPLC‐ESI‐MS/MS profiling method using a triple quadrupole MS is presented herein, which utilizes in‐source fragmentation and a pseudo‐MS3 approach for the selective analysis of flavonoid glycoconjugates with isomeric/isobaric aglycones. A selective MRM‐based identification of the in‐source formed isobaric aglycone fragments was established. Additionally, utilizing the precursor scanning capability of the employed triple quadrupole instrument, the developed method enabled the determination of the molecular weight of the studied intact flavonoid glycoconjugate. The versatility of the method was proven with various types of flavonoid aglycones, i.e. anthocyanins, flavonols, flavones, flavanones and isoflavones, along with their representative glycoconjugates. The developed method was also successfully applied to a commercially available sour cherry sample, in which 16 different glycoconjugates of pelargonidin, genistein, cyanidin, kaempferol and quercetin could be tentatively identified, including a number of compounds containing isomeric/isobaric aglycones. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
5.
Dendronized Hyperbranched Macromolecules: Soft Matter with a Novel Type of Segmental Distribution 下载免费PDF全文
Priv.‐Doz. Dr. Albena Lederer Prof. Dr. Walther Burchard Tobias Hartmann Johannes S. Haataja Dr. Nikolay Houbenov Andreas Janke Dr. Peter Friedel Dr. Ralf Schweins Dr. Peter Lindner 《Angewandte Chemie (International ed. in English)》2015,54(43):12578-12583
Dendronization of a hyperbranched polyester with different generation dendrons leads to pseudo‐dendritic structures. The hyperbranched core is modified by the divergent coupling of protected monomer units to the functional groups. Compared to dendrimers, the synthetic effort is significantly less, but the properties are very close to those of high‐generation dendrimers. The number of functional groups, molar mass, and rheology behavior even in the early generation (G1–G4) pseudo‐dendrimers strongly resembles the behavior of dendrimers in higher generations (G5–G8). Comparison of the segmental and internal structure with perfect dendrimers is performed using SANS, dynamic light scattering and viscosity analysis, microscopy and molecular dynamics simulation. The interpretation of the results reveals unique structural characteristics arising from lower segmental density of the core, which turns into a soft nano‐sphere with a smooth surface even in the first generation. 相似文献
6.
针对半片光伏组件电致发光(electroluminescence,EL)缺陷自动识别过程中训练用样本不足导致模型过拟合的问题,采用深度卷积生成对抗网络(deep convolutional generative adversarial networks,DCGANs)生成可控制属性的半片光伏组件EL图像,再采用多尺度结构相似性(multiscale structural similarity,MS-SSIM)指标对生成的EL图像与拍摄的EL图像之间的相似程度进行了评估。评估结果得到,使用DCGANs生成的所有类型半片光伏组件的EL图像与拍摄的EL图像的MS-SSIM指标都大于0.55,大部分的MS-SSIM值在0.7附近。在分类模型的训练过程中,测试集准确率随着训练集中生成图像数量的增加而升高,当生成图像数量达到6 000张时,测试集准确率达到97.92%。实验结果表明,采用DCGANs能够生成高质量且可控制属性的半片光伏组件EL图像,较好地解决因缺少训练样本而导致的模型过拟合问题。 相似文献
7.
Identification of line-of-sight (LoS)/ non-LoS (NLoS) condition in millimeter wave (mmWave) communication is important for localization and unobstructed transmission between a base station (BS) and a user. A sudden obstruction in a link between a BS and a user can result in poorly received signal strength or termination of communication. Channel features obtained by the estimation of channel state information (CSI) of a user at the BS can be used for identifying LoS/NLoS condition. With the assumption of labeled CSI, existing machine learning (ML) methods have achieved satisfactory performance for LoS/NLoS identification. However, in a real communication environment, labeled CSI is not available. In this paper, we propose a two-stage unsupervised ML based LoS/NLoS identification framework to address the lack of labeled data. We conduct experiments for the outdoor scenario by generating data from the NYUSIM simulator. We compare the performance of our method with the supervised deep neural network (SDNN) in terms of accuracy and receiver characteristic curves. The proposed framework can achieve an accuracy of 87.4% and it outperforms SDNN. Further, we compare the performance of our method with other state-of-the-art LoS/NLoS identification schemes in terms of accuracy, recall, precision, and F1-score. 相似文献
8.
Yongqiao Wang Donghe Pei Xiupeng Cui 《Mathematical Methods in the Applied Sciences》2017,40(18):7151-7161
We introduce the notions of the pseudospherical normal Darboux images for the curve on a lightlike surface in Minkowski 3‐space and study these Darboux images by using technics of the singularity theory. Furthermore, we give a relation between these Darboux images and Darboux frame from the viewpoint of Legendrian dualities. 相似文献
9.
Mohsen Miraoui 《Mathematical Methods in the Applied Sciences》2017,40(13):4716-4726
In this article, a new approach for pseudo almost periodic solution under the measure theory, under Acquistpace‐Terreni conditions. We make extensive use of interpolation spaces and exponential dichotomy techniques to obtain the existence of μ‐pseudo almost periodic solutions to some classes of nonautonomous partial evolution equations. For illustration, we propose some application to a nonautonomous heat equation. Copyright © 2017 John Wiley & Sons, Ltd. 相似文献
10.
Multicomponent reactions (MCRs) have inherent advantages in pot, atom, and step economy (PASE). This important green synthetic approach has gained increasing attention due to high efficiency, minimal waste, saving resources, and straightforward procedures. Presented in this review article are the recent development on 5-compoment reactions (5CRs) of the following six types: (I) five different molecules A + B + C + D + E; pseudo-5CRs including (II) 2A + B + C + D, (III) 2A + 2B + C, (IV) 3A + B + C, (V) 3A + 2B, and (VI) 4A + B. 5CRs with more than five-reaction centers are also included. 相似文献